Thursday, February 28, 2013

1302.6880 (Christopher J. Fullerton et al.)

Dynamical phase transitions in supercooled liquids: interpreting
measurements of dynamical activity
   [PDF]

Christopher J. Fullerton, Robert L. Jack
We study dynamical phase transitions in a model supercooled liquid. These transitions occur in ensembles of trajectories that are biased towards low (or high) dynamical activity. We compare two different measures of activity that were introduced in recent papers and we find that they are anti-correlated with each other. To interpret this result, we show that the two measures couple to motion on different length and time scales. We find that inactive states with very slow structural relaxation nevertheless have increased molecular motion on short scales. We discuss these results in terms of the potential energy landscape of the system and in terms of the liquid structure in active/inactive states.
View original: http://arxiv.org/abs/1302.6880

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